Slide 13
Slide 13 text
Many Defects but Few Carriers
Pb halide perovskites are intrinsic – low carrier
concentrations, resistant to extrinsic p or n doping
Carrier Conc. Technique Reference
109 cm-3
Hall effect on pressed
pellets of CH3
NH3
PbI3
Stoumpos et al, Inorg
Chem 52, 9019 (2013)
109 cm-3
Impedance
measurements on
photovoltaic devices
Pockett et al, J Phys
Chem C 119, 3456
(2015)
1014 cm-3
Hall effect on thin films
of CH3
NH3
PbI3
Bu et al, J Mat Chem A 2,
18508 (2014)
1014 cm-3 = 1 carrier every 10 million unit cells (high purity CdTe)