化學電池 - 池易楷 博士後研究員

化學電池 - 池易楷 博士後研究員

Transcript

1. Batteries Research Department of Aeronautics and Astronautics Yi-Kai Chih(池易楷, Kerry), Ph. D. 1
2. OUTLINE CONTENTS 01、Global view 02、Batteries 03、 Lithium titanate (LTO), Magnesium titanate (MgTO) 2
3. The award of Nobel Prize in Chemistry 2019 Global view 01 77 years old 97 years old 71 years old WHY? WHY? WHY? John B. Goodenough, born 1922 in Jena, Germany. Ph.D. 1952 from the University of Chicago, USA. Virginia H. Cockrell Chair in Engineering at The University of Texas at Austin, USA. M. Stanley Whittingham, born 1941 in the UK. Ph.D. 1968 from Oxford University, UK. Distinguished Professor at Binghamton University, State University of New York, USA. Akira Yoshino, born 1948 in Suita, Japan. Ph.D. 2005 from Osaka University, Japan. Honorary Fellow at Asahi Kasei Corporation, Tokyo, Japan and professor at Meijo University, Nagoya, Japan. 2019 Nobel Prize in Chemistry goes to inventors of lithium-ion batteries 3
4. Brief History of the Invention of Batteries 4 History Practical Challenges Associated with Catalyst Development for the Commercialization of Li-air Batteries 02 Fundamental principle
5. Brief History of the Invention of Batteries 5 History Practical Challenges Associated with Catalyst Development for the Commercialization of Li-air Batteries Over 219 years Fundamental principle
6. Voltaic pile How do they work? Overall reaction Overall reaction Galvanic cell 6
7. 19th-century illustration of Planté's original lead-acid cell In 1859, Gaston Planté invented the lead–acid battery, the first-ever battery that could be recharged by passing a reverse current through it. Lead-acid battery Zinc–Carbon battery This battery was invented by Goerge Lionel Leclanche in 1866 In 1888, Carl Gassner made a breakthrough and patented the zinc-carbon dry cell. Zn(s) + 2 MnO2(s) + 2 NH4 + (aq) → Mn2 O3(s) + Zn(NH3 )2 2+ (aq) + H2 O(l) E= 1.5 V E= 2.0 V 7
8. https://en.wikibooks.org/wiki/Introduction_to_Inorganic_Chemistry/Redox_Stability_and_Redox_Reactions Standard reduction table 8 Li Li+ + e- ΔE= +3.05 eV ΔE= -3.05 eV Enthalpy ΔE ΔE
9. Lithium battery-M. Staley Whittingham 9 TiS2 https://www.sciencenews.org/article/lithium-ion-battery-chemistry-nobel-prize JOHAN JARNESTAD / THE ROYAL SWEDISH ACADEMY OF SCIENCES
10. Lithium battery-John B. Goodenough 10 https://www.sciencenews.org/article/lithium-ion-battery-chemistry-nobel-prize JOHAN JARNESTAD / THE ROYAL SWEDISH ACADEMY OF SCIENCES
11. 11 Lithium-ion battery-Akira Yoshino https://www.sciencenews.org/article/lithium-ion-battery-chemistry-nobel-prize JOHAN JARNESTAD / THE ROYAL SWEDISH ACADEMY OF SCIENCES replace
12. Lithium-ion battery overview https://www.semanticscholar.org/paper/The-Li-ion-rechargeable-battery%3A-a-perspective.-Goodenough- Park/42e965ce07774bc11bf7b270b6249bda7c510fc9 12
13. Anode Electrolyte cathode Voltage (eV) Voltaic pile Zn NaCl, KNO3 Cu 1.1 eV Lead-acid battery Pb H2 SO4 PbO2 2.0 eV Zinc–Carbon battery Zn MnO2 , NH4 Cl, ZnCl2 Carbon 1.5 eV Lithium battery (M. Staley Whittingham) Li Li+ TiS2 2.0 eV Lithium battery (John B. Goodenough) Li metal Li+ Cobalt oxide 4.0 eV Lithium-ion battery (Akira Yoshino) Petroleum coke (Li+) Li+ Cobalt oxide 4.0 eV Lithium-ion battery Graphite (Lix C6 ) Li+ Lix CoO2 Lix Mn2 O4 Lix FePO4 3.5-4.2 eV Power (J/s) = Volt. x current = V (J/C) x I (C/s) Total $/s = $/people x people/s List of some anode, electrolyte, and cathode materials for Li-ion batteries For 30 years, lithium has yet to be superseded by any other element. 13
14. Lithium titanate (LTO) Magnesium titanate (MgTO) 14
15. https://en.wikibooks.org/wiki/Introduction_to_Inorganic_Chemistry/Redox_Stability_and_Redox_Reactions Standard reduction table 15 Li Li+ + e- ΔE= +3.05 eV ΔE= -3.05 eV Enthalpy ΔE ΔE
16. Magnesium titanate (MgTO) 16 (MgTO) (Mg-base) Mg+2
17. THANK YOU